Abstract:A new approach has been used to minimize surface degradation of the LiMn₂O₄ cathode in lithium ion batteries by using surface modification. LiMn₂O₄ particles used as active material in cathode fabrication were modified by surface adsorption of poly(diallyldimethylammonium chloride) (PDDA). Adsorption and electrochemical performance of the modified cathode material were characterized and compared with that of the untreated LiMn₂O₄-based cathode. Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis (EDAX) analyses confirmed the formation of a thin polymer film on the surface of LiMn₂O₄ particles. The modified LiMn₂O₄–based cathode showed improved stability during charge/discharge cycling in organic electrolyte at room temperature. Further, the measured capacity fading after storage at elevated temperature decreased. Capacity fading measured on cathodes made of PDDA-coated LiMn₂O₄ powder was smallest for cathodes obtained from powder coated in solutions containing between 30 and 50 mM PDDA. In situ AFM observation of the cathodes at room temperature showed minor changes in surface topography during a potential cycle. Our hypothesis is that the adsorbed polymer layer blocks surface reactions that cause degradation. The present method for surface modified LiMn₂O₄ (SM-LMO) particles extends the lifetime of the lithium-ion battery by arresting the Mn⁺ dissolution, thereby increasing the battery stability.