Suggested Citation:
Kleeman, Michael J. (2024)

Brief: On-Road Motor Vehicles No Longer Dominate Ozone Formation

The amount of traffic on California’s roadways decreased by approximately fifty percent during the COVID-19 pandemic lockdown in March and April of 2020. Conventional wisdom led to the expectation that reduced traffic would result in reduced ozone (O3) concentrations—ozone being a main component of smog—yet ozone concentrations increased during this period. Internal combustion vehicles emit oxides of nitrogen (NOx) and volatile organic compounds (VOCs). These emissions are precursors for ozone formation, but the relationship between these precursor emissions and the final ozone concentration is complex. The ratio of NOx/VOCs determines if the ozone formation will be “NOx-limited” or “NOx-rich”. Major NOx reductions are required to reduce ozone concentrations when the atmosphere is NOx-rich. Small NOx reductions in a NOx-rich atmosphere can actually increase ozone concentrations.

This policy brief is drawn from the report  “Measuring Changes in Air Quality from Reduced Travel in Response to COVID-19” available at: www.ucits.org/research-project/2021-07.